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郑彦龙

发布者:朱珊 [发表时间]:2021-03-17 [来源]: [浏览次数]:

郑彦龙博士,副研究员

通讯地址:天津理工大学,生命健康智能检测研究院18号楼304

E-mail:ylzheng@email.tjut.edu.cn

教育及科研经历

2021.1—至今,天津理工大学,生命健康智能检测研究院,副研究员

2018.02—2020.09, University of Ottawa,博士后合作导师:Stephen G. Newman

2014.09—2017.06南开大学,有机化学博士,导师:叶萌春

2011.09—2014.06南开大学,有机化学硕士,导师:汪清民

2007.09—2011.06安阳师范学院,材料化学,理学学士

 

研究方向

1、丰产过渡金属铁钴镍等催化的烯烃和炔烃的官能化反应,亲电试剂还原偶联等有机合成方法学研究。

2、生物活性小分子的设计、合成以及其生物活性研究。

主持项目

1、国家自然科学基金青年项目,镍和钴共催化非活化烯烃的还原型双碳官能团化反应研究,22101203,2022-01—2024-12,主持,在研。

发表论文

14、Zheng, Y.-L.;* Liang, D.-Y.; Ma, H.-B.; Meng, F.-C.; Wang, T.* Regio- and chemoselective hydroamination of unactivated alkenes with anthranils via NiH-catalysis. Chem. Commun., 2023, doi: 10.1039/d2cc07052a.s

13、Tao, S.-C.; Meng, F.-C.; Wang, T.;* Zheng, Y.-L.* Ni-catalyzed arylation of alkynes with organoboronic acids and aldehydes to access stereodefined allylic alcohols. Chem. Sci., 2023, 14, 2040–2045.

12、Zheng, Y.-L.; Xie, P.-P.; Daneshfar, O.; Houk, K. N.;* Hong, X.;* Newman, S. G.* Direct Synthesis of Ketones from Methyl Esters by Nickel-Catalyzed Suzuki-Miyaura Coupling.Angew. Chem. Int. Ed.2021,60, 13476–13483.

11、Zheng, Y.-L.; Newman, S. G.* Cross-coupling reactions with esters, aldehydes, and alcohols.Chem. Commun.2021,57, 2591–2604.

10、Cook, A.; Prakash, S.;Zheng, Y.-L.;Newman, S. G.* Exhaustive Reduction of Esters Enabled by Nickel Catalysis.J. Am. Chem. Soc.2020,142, 8109–8115.

9、Zheng, Y.-L.;Ye, M.* Nickel-Catalyzed Reductive Coupling of Aldehydes with Alkynes Mediated by Alcohol.Chin. J. Chem.2020,38, 489–493.

8、Zheng, Y.-L.;Newman, S. G.* Nickel-Catalyzed Domino Heck-Type Reactions using Methyl Esters as Cross-Coupling Electrophiles.Angew. Chem. Int. Ed.2019,58, 18159–18164.

7、Zheng, Y.-L.; Newman, S. G.*Methyl Esters as Cross-Coupling Electrophiles: Direct Synthesis of Amide Bonds.ACS Catal.2019,9, 4426–4433.

6、Zheng, Y.-L.; Liu, Y.-Y.; Xu, X.-T.; Zhang, K.;* Ye, M.* Iron-Catalyzed Intramolecular Reductive Coupling of Unactivated Aldehydes and Arylalkenes with Isopropanol.Asian J. Org. Chem.2018,7, 554–557.

5、Han, X.-W.; Zhang, T.;Zheng, Y.-L.; Yao, W.-W.; Li, J.-F.; Pu, Y.-G.; Ye, M.;* Zhou, Q.-L. Brønsted Acid Enabled Nickel-Catalyzed Hydroalkenylation of Aldehydes with Styrene and its Derivatives.Angew. Chem. Int. Ed.2018,57, 5068–5071.

4、Zheng, Y.-L.;Luan, Y.-X.; Ye, M.* Recent Progress in Base Metal Catalyzed (Transfer) Hydrogenative Couplings of Carbonyls with π-Unsaturated Compounds.Synlett2016,27,2401–2406.

3、Zheng, Y.-L.;Liu, Y.-Y.; Wu, Y.-M.; Wang, Y.-X.; Lin, Y.-T.; Ye, M.* Iron-Catalyzed Regioselective Transfer Hydrogenative Couplings of Unactivated Aldehydes with Simple Alkenes.Angew. Chem. Int. Ed.2016,55, 6315–6318.

2、Zheng, Y.-L; Liu, Y.; Wang, Q.* Collective Asymmetric Synthesis of (−)-Antofine, (−)-Cryptopleurine, (−)-Tylophorine, and (−)-Tylocrebrine withtert-Butanesulfinamide as a Chiral Auxiliary.J. Org. Chem.,2014,79, 3348–3357.

1、Li, Y.; Li, C.;Zheng, Y.-L; Wei, X.; Ma, Q.; Wei, P.; Liu, Y.; Qin, Y.; Yang, N.; Sun, Y.; Ling, Y.; Yang, Xin.;* Wang, Q.* Design, Synthesis, Acaricidal Activity, and Mechanism of Oxazoline Derivatives Containing an Oxime Ether Moiety.J. Agric. Food. Chem.2014,62, 3064–3072.